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g 1 , because beyond this region the exponential factor gives a decrease in the level of more than 10 dB. Figure 7.20 also shows the limitation of the working scattered volume due to the spatial antenna radiation patterns. The ellipses ET and ER represent the intersection of the antenna diagrams by the horizontal plane plotted at the center of the active scattering zone at the height of about 100 km above the Earth s surface. From the corresponding experiments carried out at the middlelatitude radio traces, it follows that the height of HE signals is ranged between 100 and 110 km. We can assume that the effective height of the working volume at the vertical plane is about 5 km and therefore, can be regarded as a cylindrical body aligned along the geomagnetic eld lines. The same derivations can be done for the burst-like signals, which are most likely of meter origin. In this case, in formula (7.121) one should con ne oneself to a volume VF , where half of the Fresnel zone forms s lrT rR VF S rT rR 1 cos2 b sin2

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Rate Constant 104 (L mol 1 s 1) 14.63 7.81 13.50 10.21 13.45 21.34 8.43

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Table 2-10 shows the rate constants for the various reactions. It is apparent that there are signi cant differences in the reactivities of the different functional groups in phenol (i.e., in the different positions on the ring). The reaction between phenol and formaldehyde involves a nucleophilic attack by the phenolate anion on formaldehyde (Eq. 2-174) (or its hydrated form). The electron-pushing methylol groups generally increase the reactivity of phenol toward further substitution although steric hindrance modi es this effect. It is dif cult to quantitatively discuss the reasons for the speci c differences in reactivity, since there is no general agreement on even the relative values of the seven different rate constnats. The evaluation of the different rate constants is dif cult from both the viewpoints of chemical analysis of the mono-, di-, and trimethylolphenols and the mathematical analysis [Katz and Zwei, 1978] of the kinetic data.

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7:122

2-174

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Here, S is the effective area of scattering (cross section) of an inhomogeneity; b is the angle between the direction of the inhomogeneity and the TQR-plane; and 2F is the angle TQR (see Fig. 7.19). As the cross section S, it is reasonable to take the area of the circle whose diameter equals the radius of the cross-correlation lopt . Considering that

Not only are the different ring positions on phenol of different reactivity, but one expects that the two functional groups of formaldehyde would also differ. The second functional group of formaldehyde actually corresponds to the methylol group, since the reaction of a methylolphenol with a phenol molecule (or with a second methylolphenol) probably proceeds by a sequence such as

Typically, you will set the error provider error message in response to the Validating event discussed earlier For example, if you want to validate the user's password when the focus leaves the password text box, you could have a handler for the Validating event that looks like this: private void OnPasswordValidating(object sender, CancelEventArgs e) { if (!stringIsNullOrEmpty(m_UsernameTextBoxText) && !CheckPasswordForUser()) { m_ErrorProviderSetError(m_PasswordTextBox, "Password is incorrect"); } else { m_ErrorProviderSetError(m_PasswordTextBox, null); } }

2-175

N0

Direct kinetic measurements are not available to show the reactivity of the methylol group in this reaction compared to the initial reaction of formaldehyde. However, the general observation that the amounts of di- and polynuclear compounds present in resole prepolymers differ widely depending on the reaction condition (temperature, pH, speci c catalyst used, concentrations of reactants) indicates that the two functional groups of formaldehyde differ in reactivity. A further complication in the phenol-formaldehyde polymerization is that it may involve a decrease in functional group reactivity with molecular size. This can easily happen in systems that undergo extensive crosslinking. Such systems may cease to be homogeneous solutions before the experimentally determined gel point. The gel point may be preceded by the formation of microgel particles (Sec. 2-2d) which are too small to be visible to the naked eye [Katz and Zwei, 1978]. Functional groups in the microgel particles would be relatively unreactive because of their physical unavailability. Similar considerations would apply for the reaction period subsequent to the gel point. A decrease in reactivity with size may not be due to molecular size but a consequence of steric shielding of ortho or para positions of benzene rings within a chain compared to those positions on rings at the chain ends [Kumar et al., 1980].

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