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The process by which certain porous solids bind large numbers of molecules to their surfaces is known as adsorption Not only does it serve as a separation process, but it is also a vital part of catalytic-reaction processes As a separation process, adsorption is used most often for removal of low-concentrationimpurities and pollutants from fluid streams It is also the basis for chromatographyIn surface-catalyzedreactions, the initial step is adsorption of reactant species; the final step is the reverse process, desorption of product species Since most industrially important reactions are catalytic, adsorption plays a fundamental role in reaction engineering The nature of the adsorbing surface is the determining factor in adsorption The molecular characterization of solid surfaces is not yet fully developed; however, current knowledge allows a helpful description To be useful as an adsorbent, a solid must present a large surface area per unit mass (up to 1500 m2 per gram) This can only be achieved with porous solids such as activated carbon, silica gels, aluminas, and zeolites, which contain many cavities or pores with diameters as small as a fraction of a nanometer Surfaces of such solids are necessarily irregular at the molecular level, and they contain sites of particular attraction for adsorbing molecules If the sites are close together, the adsorbed molecules may interact with one another; if they are sufficiently dispersed, the adsorbed molecules may interact only with the sites Depending upon the strength of the forces binding them to the sites, these adsorbate molecules may be mobile or fixed in position The relatively weak electrostatic, induction, and dispersion forces discussed in Sec 161 favor mobility and result in physical adsorption On the other hand, much stronger quasichemical forces can act to fix molecules to the surface, promoting chernisorption Although adsorption may be classified in several ways, the usual distinction is between physical adsorption and chemisorption Based on the strength of the binding forces, this division is observed experimentally in the magnitudes of the heat of adsorption In the adsorption of gases, the number of molecules attracted to a solid surface depends on conditions in the gas phase For very low pressures, relatively few molecules are adsorbed, and only a fraction of the solid surface is covered As the gas pressure increases at a given temperature, surface coverage increases When all sites become occupied, the adsorbed molecules are said to form a monolayer Further increase in pressure promotes multilayer adsorption It is also possible for multilayer adsorption to occur on one part of a porous surface when vacant sites still remain on another part The complexities of solid surfaces and our inability to characterize exactly their interactions with adsorbed molecules limits our understanding of the adsorption process It does not, however, prevent development of an exact thermodynamic description of adsorption equilibrium, applicable alike to physical adsorption and chemisorption and equally to monolayer and multilayer adsorption The thermodynamic framework is independent of any particular theoretical or empirical description of material behavior However, in application such a description is essential, and meaningful results require appropriate models of behavior. asp net mvc 6 pdf Asp . Net PDF Viewer Control - Webforms MVC .NET Core
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